Dimethylformamide dimethyl acetal → HCID 53940560, compound

HRID 2393043Notes

Reaction equation

HRID 2393043 reaction equation
CO[CH:3](OC)[N:4]([CH3:6])[CH3:5].[CH:9]1([C:12](=[O:25])[CH2:13][C:14]([C:16]2[CH:21]=[CH:20][C:19]([CH3:22])=[C:18]([S:23][CH3:24])[CH:17]=2)=[O:15])[CH2:11][CH2:10]1>C1(C)C=CC=CC=1>[CH:9]1([C:12](=[O:25])[C:13](=[CH:3][N:4]([CH3:5])[CH3:6])[C:14]([C:16]2[CH:21]=[CH:20][C:19]([CH3:22])=[C:18]([S:23][CH3:24])[CH:17]=2)=[O:15])[CH2:11][CH2:10]1

Participants

4

Reactant 2

HCID 78373Dimethylformamide dimethyl acetal2×HCID 18978019HCID 18978019, compound

Product 1

HCID 53940560HCID 53940560, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

Dimethyl formamide dimethyl acetal (6.0 ml) was added to a solution of 3-cyclopropyl-1-(4-methyl-3-methylsulphenylphenyl)propan-1,3-dione (8.71 g) in toluene. The mixture was stirred at room temperature overnight. Further dimethyl formamide dimethyl acetal (2.0 ml) was added and the mixture was stirred and heated at 50° C. for 24 hours. It was cooled and evaporated to dryness to give 3-cyclopropyl-2-(N,N-dimethylaminomethylene)-1-(4-methyl-3-methylsulphenylphenyl)propan-1,3-dione (10.6 g) as a brown oil.

Workup

  1. stirringthe mixture was stirred
  2. temperatureheated at 50° C. for 24 hours
  3. temperatureIt was cooled
  4. customevaporated to dryness

Sources & evidence

ORD record
ord-c62f731823f74010b4c420b549576e78
Source dataset
uspto-grants-1998_09
Patent number
US05804532

Reaction notes

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