HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzoyl chloride → 2-((Phenyl)carbonyl)amino-7-nitrotetralin
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzoyl chloride | HCID 7412 | — |
| Reactant | 7-Nitro-1,2,3,4-tetrahydronaphthalen-2-amine | HCID 23298421 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Solvent | Potassium Carbonate | HCID 11430 | — |
| Product | 2-((Phenyl)carbonyl)amino-7-nitrotetralin | HCID 23298409 | — |
Reaction Steps
To 2-amino-7-nitrotetralin (2.8 g, 14.5 mmol) in THF (50 ml) and 10% K2CO3 (100 ml) was added benzoyl chloride (1.7 ml, 15.3 mmol). After the addition was complete, the mixture was diluted with water to a volume of 250 ml. The precipitated solids were collected by filtration, washed with water, and dried in vacuo: (4.2 g, 98%), m.p. 194°-198° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05807886 |
| Source dataset | uspto-grants-1998_09 |
| ORD ID | ord-784cb836c42e4348b068a4944eb2d15f |
| Source note | uspto-grants-1998_09 |