HCID 136351329, compound → HCID 178469225, compound

HRID 2394299Notes

Reaction equation

HRID 2394299 reaction equation
[Cl:1][C:2](=[C:14]([Cl:16])Cl)[C:3]([OH:13])=[C:4]([C:10](=[NH:12])[CH3:11])[C:5]([O:7][CH2:8][CH3:9])=[O:6]>ClC1C=CC=CC=1Cl>[Cl:1][C:2]1[C:14]([Cl:16])=[N:12][C:10]([CH3:11])=[C:4]([C:3]=1[OH:13])[C:5]([O:7][CH2:8][CH3:9])=[O:6]

Participants

3

Reactant 1

HCID 136351329HCID 136351329, compound

Product 1

HCID 178469225HCID 178469225, compound

Reagents, catalysts & solvents 1

HCID 72391,2-DichlorobenzeneSolvent

Procedure

102.7 g (0.35 mol) of ethyl 4,5,5-trichloro-3-hydroxy-2-(1-imino-ethyl)penta-2,4-dienoate are heated at 180° C. in 1,2-dichlorobenzene for three hours. The volatile components are removed under a high vacuum up to 100° C. The residue is purified with dichloromethane on silica gel.

Workup

  1. customThe volatile components are removed under a high vacuum up to 100° C
  2. customThe residue is purified with dichloromethane on silica gel

Sources & evidence

ORD record
ord-4fc64a4759fd49dbb8342f29b0d0376b
Source dataset
uspto-grants-1998_09
Patent number
US05811433

Reaction notes

Loading…