HRID2395018

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：O=C(O)c1ccc(CCCc2ccccc2OCc2ccccc2)cc1

HCID18973764

未命名化合物

结构：COc1cc(/C=C/c2ccccc2OCc2ccccc2)ccc1C(=O)O

HCID18973900

未命名化合物

结构：COC(=O)c1ccc(CCCc2ccccc2OCc2ccccc2)cc1

HCID18973910

未命名化合物

$结构：COC(=O)c1ccc(/C=C\c2ccccc2OCc2ccccc2)cc1OC$

HCID70347226

未命名化合物

PRODUCTS

生成物

$结构：COc1cc(/C=C\c2ccccc2OCc2ccccc2)ccc1C(=O)O$

HCID70346838

未命名化合物

PROCEDURE

实验过程

Methyl 4-[2-(2-benzyloxyphenyl)-(Z)-ethenyl]-2-methoxy-benzoate (obtained from methyl 4-[2-(2-benzyloxyphenyl)-(Z)-ethenyl]-2-hydroxybenzoate as described in Example 14) was converted to 4-[2-(2-benzyloxyphenyl)-(E)-ethenyl]-2-methoxybenzoic acid (containing 15% of the (Z) isomer and obtained as a gum; negative FAB mass peak 359) using the method described in Example 1 for the conversion of methyl 4-[3-(2-benzyloxyphenyl)propyl]benzoate to 4-[3-(2-benzyloxyphenyl)-propyl]benzoic acid.

WORKUP

后处理

customobtained as a gum