HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanol → Dimethyl 2,4-dichloroisophthaloate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanol | HCID 887 | — |
| Reactant | 2,4-Dichloro-3-methoxycarbonylbenzoylchloride | HCID 18989156 | — |
| Product | Dimethyl 2,4-dichloroisophthaloate | HCID 18989135 | — |
Reaction Steps
2,4-Dichloro-3-methoxycarbonylbenzoylchloride (34.76 g) was stirred and heated under reflux with methanol for 15 hours. After cooling, the solvent was evaporated and the residue recrystallised from cyclohexane to give dimethyl 2,4-dichloroisophthaloate (16.04 g) as a beige solid, NMR (DMSO D6) δ3.87 (3H,s), 3.94 (3H,s), 7.74 (1H,d), 7.94 (1H,d).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05489570 |
| Source dataset | uspto-grants-1996_02 |
| ORD ID | ord-50de8a8e5889458aa897d22b26e783fe |
| Source note | uspto-grants-1996_02 |