HuagongsheHuagongshe Chemistry Print Report · For research reference only
3-Bromo-4-methoxybenzaldehyde → Methyl 3-bromo-4-methoxy-alpha-azidocinnamate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3-Bromo-4-methoxybenzaldehyde | HCID 98662 | — |
| Reactant | Methyl 2-azidoacetate | HCID 4020482 | — |
| Product | Methyl 3-bromo-4-methoxy-alpha-azidocinnamate | HCID 53891859 | — |
Reaction Steps
Following the general procedure of PREPARATION 61 and making non-critical variations but starting with 3-bromo-4-methoxybenzaldehyde (5.0 g) and methyl azidoacetate (10.7 g), the title compound is obtained, NMR (300 MHz, CDCl3) 8.10, 7.73, 6.89, 6.79, 3.94 and 3.90 δ.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05489593 |
| Source dataset | uspto-grants-1996_02 |
| ORD ID | ord-a3550366f6244ad6a8e36db0a3736886 |
| Source note | uspto-grants-1996_02 |