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HRID2395768

反应详情

EQUATION

反应方程式

HRID 2395768 的结构方程式

REACTANTS

反应物

2
结构：COc1ccc(C=O)cc1Br
HCID98662

3-Bromo-p-anisaldehyde

C8H7BrO2

结构：COC(=O)CN=[N+]=[N-]
HCID4020482

Methyl 2-azidoacetate

C3H5N3O2

PRODUCTS

生成物

1
结构：COC(=O)C(=Cc1ccc(OC)c(Br)c1)N=[N+]=[N-]
HCID53891859

Methyl 2-azido-3-(3-bromo-4-methoxyphenyl)-2-propenoate

C11H10BrN3O3

PROCEDURE

实验过程

Following the general procedure of PREPARATION 61 and making non-critical variations but starting with 3-bromo-4-methoxybenzaldehyde (5.0 g) and methyl azidoacetate (10.7 g), the title compound is obtained, NMR (300 MHz, CDCl3) 8.10, 7.73, 6.89, 6.79, 3.94 and 3.90 δ.

WORKUP

后处理

  1. customthe general procedure of PREPARATION 61