2-Octanol → 2-octanol, tBDMS

HRID 2396586Notes

Reaction equation

HRID 2396586 reaction equation
[Si:1](Cl)([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:3])[CH3:2].[CH3:9][CH:10]([OH:17])[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]>C1CCCCC1>[Si:1]([O:17][CH:10]([CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16])[CH3:9])([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:3])[CH3:2]

Participants

4

Reactant 2

HCID 200832-OctanolHCID 28928tert-Butyldimethylsilyl chloride

Product 1

HCID 64302382-octanol, tBDMS

Reagents, catalysts & solvents 1

HCID 8078CyclohexaneSolvent

Procedure

Analysis of this material by GC indicated it was 96.9% assay product. addition, the stripped solution contained 1.1% cyclohexane, 0.04% t-butyldimethylsilyl chloride, 0.3% 2-octanol, and 1.7% unknowns.

Workup

  1. additionaddition

Sources & evidence

ORD record
ord-e90ae74e88804c2ba10771a430973c95
Source dataset
uspto-grants-1996_02
Patent number
US05493044

Reaction notes

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