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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2396661Generated: October 30, 2026

4-Bromo-2-fluoro-1-(4-octoxyphenyl)benzene → 4,4"-Dioctyloxy-3,3'-difluoro-p-terphenyl

https://huagongshe.com/reaction/2396661

Reaction equation

Participants

RoleNameHCIDCharge
Reactant4-Bromo-2-fluoro-1-(4-octoxyphenyl)benzeneHCID 1715664—
ReactantBenzene, 4-bromo-2-fluoro-1-(octyloxy)-HCID 3581959—
Reactant4-Octyl-2'-fluoro-4'-bromobiphenylHCID 14766292—
Reactant(R)-4-(1-methylhexyl)oxy-3-fluorobromobenzeneHCID 14766296—
Product4,4"-Dioctyloxy-3,3'-difluoro-p-terphenylHCID 1476627813.9%

Reaction Steps

Except that 3.6 g of 4-octyloxy-3-fluorobromobenzene obtained in Example 3 (a) and 2.2 g of 4-octyloxy-2'-fluoro-4'-bromobiphenyl obtained in Example 2 (c) were used in place of 3.4 g of (R) -4-(1-methylhexyl)oxy-3-fluorobromobenzene and 2.2 g of 4-octyl-2'-fluoro-4 '-bromobiphenyl used in Example 1 (e), respectively, the operation was performed in the same manner as in Example 1 (e) to obtain 0.42 g (13.9%) of 4,4"-dioctyloxy-3,3 '-difluoro-p-terphenyl.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS05494605
Source datasetuspto-grants-1996_02
ORD IDord-b9d4ec140a7143d9bab6c549882de81f
Source noteuspto-grants-1996_02