HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Bromo-2-fluoro-1-(4-octoxyphenyl)benzene → 4,4"-Dioctyloxy-3,3'-difluoro-p-terphenyl
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Bromo-2-fluoro-1-(4-octoxyphenyl)benzene | HCID 1715664 | — |
| Reactant | Benzene, 4-bromo-2-fluoro-1-(octyloxy)- | HCID 3581959 | — |
| Reactant | 4-Octyl-2'-fluoro-4'-bromobiphenyl | HCID 14766292 | — |
| Reactant | (R)-4-(1-methylhexyl)oxy-3-fluorobromobenzene | HCID 14766296 | — |
| Product | 4,4"-Dioctyloxy-3,3'-difluoro-p-terphenyl | HCID 14766278 | 13.9% |
Reaction Steps
Except that 3.6 g of 4-octyloxy-3-fluorobromobenzene obtained in Example 3 (a) and 2.2 g of 4-octyloxy-2'-fluoro-4'-bromobiphenyl obtained in Example 2 (c) were used in place of 3.4 g of (R) -4-(1-methylhexyl)oxy-3-fluorobromobenzene and 2.2 g of 4-octyl-2'-fluoro-4 '-bromobiphenyl used in Example 1 (e), respectively, the operation was performed in the same manner as in Example 1 (e) to obtain 0.42 g (13.9%) of 4,4"-dioctyloxy-3,3 '-difluoro-p-terphenyl.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05494605 |
| Source dataset | uspto-grants-1996_02 |
| ORD ID | ord-b9d4ec140a7143d9bab6c549882de81f |
| Source note | uspto-grants-1996_02 |