O-Phenylenediamine → N~1~,N~1~,N~2~,N~2~-Tetrakis(3-methylphenyl)benzene-1,2-diamine

HRID 2396669Notes

Reaction equation

[C:1]1([NH2:8])[CH:6]=[CH:5][CH:4]=[CH:3][C:2]=1[NH2:7].I[C:10]1[CH:11]=[C:12]([CH3:16])[CH:13]=[CH:14][CH:15]=1>>[CH3:16][C:12]1[CH:11]=[C:10]([N:7]([C:10]2[CH:15]=[CH:14][CH:13]=[C:12]([CH3:16])[CH:11]=2)[C:2]2[CH:3]=[CH:4][CH:5]=[CH:6][C:1]=2[N:8]([C:10]2[CH:15]=[CH:14][CH:13]=[C:12]([CH3:16])[CH:11]=2)[C:10]2[CH:15]=[CH:14][CH:13]=[C:12]([CH3:16])[CH:11]=2)[CH:15]=[CH:14][CH:13]=1

Participants

Reactant 2

HCID 7243O-Phenylenediamine

HCID 122683-Iodotoluene

Product 1

HCID 18985805N~1~,N~1~,N~2~,N~2~-Tetrakis(3-methylphenyl)benzene-1,2-diamine

Procedure

The procedure of Example 1 was repeated except the use of 5.4 g of o-phenylenediamine of the formula (12) and 42.6 g of m-iodotoluene of the formula (14): ##STR11## as a starting material to obtain the expected compound of the formula (4) (12.6 g, yield: 55.1%).

Sources & evidence

ORD record: ord-736041858eb54ca8a1d2a9b255171609
Source dataset: uspto-grants-1996_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05494765

Reaction notes

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