N-Octylaniline → N'-(4-Ethoxycarbonylphenyl)-N-(n-octyl)-N-phenylformamidine

HRID 2397305Notes

Reaction equation

HRID 2397305 reaction equation
[CH2:1]([O:3][C:4]([C:6]1[CH:11]=[CH:10][C:9]([N:12]=[CH:13]OCC)=[CH:8][CH:7]=1)=[O:5])[CH3:2].[CH2:17]([NH:25][C:26]1[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=1)[CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24]>C(O)C>[CH2:1]([O:3][C:4]([C:6]1[CH:7]=[CH:8][C:9]([N:12]=[CH:13][N:25]([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[C:26]2[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=2)=[CH:10][CH:11]=1)=[O:5])[CH3:2]

Participants

4

Reactant 2

HCID 137788N-OctylanilineHCID 12423501Ethyl N-(4-ethoxycarbonylphenyl)formimidate

Product 1

HCID 12423511N'-(4-Ethoxycarbonylphenyl)-N-(n-octyl)-N-phenylformamidine

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

Ethyl N-(4-ethoxycarbonylphenyl)formimidate (Example Ia) (6.6 g, 0.03 mol) and N-octylaniline (6.2 g, 0.03 mol) were heated at 180° until 1.7 ml of ethanol had been collected by distillation. The resulting pale yellow oil was flash distilled to yield the desired product, bp≈235° C. (0.05 mm). ##STR15##

Workup

  1. distillationhad been collected by distillation
  2. distillationdistilled

Sources & evidence

ORD record
ord-8b594beb6fcf4a27b76ac526cc19ea8e
Source dataset
uspto-grants-1977_05
Patent number
US04021471

Reaction notes

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