Acetic Acid → HCID 20313274, compound

HRID 2397572Notes

Reaction equation

HRID 2397572 reaction equation
[CH2:1]([C:3]1[CH2:4][NH:5][CH:6]=[C:7]([CH2:9][CH3:10])[CH:8]=1)[CH3:2].C(C1C(CC)=CC(CC)=CN=1)CC.[C:24]([OH:27])(=[O:26])[CH3:25]>>[C:24]([O-:27])(=[O:26])[CH3:25].[CH2:1]([C:3]1[CH:4]=[NH+:5][CH:6]=[C:7]([CH2:9][CH3:10])[CH:8]=1)[CH3:2]

Participants

4

Reactant 3

HCID 176Acetic AcidHCID 785313,5-Diethyl-2-propylpyridineHCID 20254595HCID 20254595, compound

Product 1

HCID 20313274HCID 20313274, compound

Procedure

To a mixture of 140 grams of 1-Butyl, 2-propyl, 3,5-diethyl 1,2-dihydropyridine and 2-propyl 3,5-diethylpyridine prepared as described in example 1 was added 18 grams of acetic acid, the mixture was stirred for 18 hours at ambient temperature in the presence of air. The resulting reaction product was extracted with water. The water insoluble fraction was identified as 2-propyl 3,5-diethylpyridine. The aqueous extract was evaporated under diminished pressure to yield 71 grams of N-Butyl, 2-propyl, 3,5-diethylpyridinium acetate, nuclear magnetic resonance spectrum, solvent CCl4. δ in ppm, 9.20 m, 1H; 8.33, m, 1H; 4.78 m, 2H; 2.95, m, 6H; 1.80 s, 3H; 1.33, m, and 0.99 m, 18H.

Workup

  1. customprepared
  2. customThe resulting reaction product
  3. extractionwas extracted with water
  4. extractionThe aqueous extract
  5. customwas evaporated under diminished pressure

Sources & evidence

ORD record
ord-0d41646ca9a845f891b3cbb38d14b1d6
Source dataset
uspto-grants-1977_05
Patent number
US04022785

Reaction notes

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