Hexamethylenediamine → HCID 21332364, compound

HRID 2397800Notes

Reaction equation

HRID 2397800 reaction equation
[CH2:1]1[O:8][CH:2]1[CH2:3][CH2:4][CH2:5][CH2:6][CH3:7].[NH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][NH2:16]>C(O)C>[CH2:15]([NH:16][CH2:1][CH:2]([OH:8])[CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][NH:9][CH2:1][CH:2]([OH:8])[CH2:3][CH2:4][CH2:5][CH2:6][CH3:7]

Participants

4

Reactant 2

HCID 16402HexamethylenediamineHCID 922152-Pentyloxirane

Product 1

HCID 21332364HCID 21332364, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

In a manner similar to that of Example 1, condensation of 1-heptene oxide (71.8 g.) and hexamethylenediamine (32 g.) and recrystallization of the resulting product from ethanol gave N,N'-(1,6-hexylene)-bis[2-hydroxyheptylamine] (I: R= CH3 (CH2)4, R' = H, X= (CH2)6, Z= H) (16.5 g., m.p. 131.2°-134.2° C.).

Sources & evidence

ORD record
ord-59331d7f75264d17986726ef4ccea230
Source dataset
uspto-grants-1977_05
Patent number
US04022833

Reaction notes

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