Hexamethylenediamine → HCID 21332375, compound

HRID 2397801Notes

Reaction equation

HRID 2397801 reaction equation
[CH2:1]1[O:9][CH:2]1[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[NH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][NH2:17]>CO>[CH2:16]([NH:17][CH2:1][CH:2]([OH:9])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8])[CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][NH:10][CH2:1][CH:2]([OH:9])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

Participants

4

Reactant 2

HCID 16402HexamethylenediamineHCID 181262-Hexyloxirane

Product 1

HCID 21332375HCID 21332375, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

In a manner similar to that of Example 1, condensation of 1-octene oxide (42 g.) and hexamethylenediamine (19.05 g.) and recrystallization of the resulting product from methanol gave N,N'-(1,6-hexylene)-bis[2-hydroxyoctylamine] (I: R= CH3 (CH2)5, R' = H, X= (CH2)6, Z= H) (17.2 g., m.p. 124.0°-127.4° C.).

Sources & evidence

ORD record
ord-bd6a00f7a6694f9783a8ec47b0082aef
Source dataset
uspto-grants-1977_05
Patent number
US04022833

Reaction notes

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