Hexamethylenediamine → HCID 21332370, compound

HRID 2397807Notes

Reaction equation

HRID 2397807 reaction equation
[CH2:1]1[O:16][CH:2]1[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15].[NH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][NH2:24]>C(O)(C)C>[CH2:23]([NH:24][CH2:1][CH:2]([OH:16])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15])[CH2:22][CH2:21][CH2:20][CH2:19][CH2:18][NH:17][CH2:1][CH:2]([OH:16])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15]

Participants

4

Reactant 2

HCID 16402HexamethylenediamineHCID 86768Oxirane, 2-tridecyl-

Product 1

HCID 21332370HCID 21332370, compound

Reagents, catalysts & solvents 1

HCID 3776IsopropanolSolvent

Procedure

In a manner similar to that of Example 1, condensation of 1-pentadecene oxide (81.7 g.) and hexamethylenediamine (21 g.) and recrystallization of the resulting product (74.3 g.) from isopropyl alcohol gave N,N'-(1,6-hexylene)-bis[2-hydroxypentadecylamine] (I: R= CH3 (CH2)12, R' = H, X = (CH2)6, Z= H) (m.p. 117.4°-124.0° C.).

Sources & evidence

ORD record
ord-59b0dc58a82940f9954b4c8e102f1c87
Source dataset
uspto-grants-1977_05
Patent number
US04022833

Reaction notes

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