Hydrogen Bromide → HCID 21332375, compound

HRID 2397813Notes

Reaction equation

Br.[CH2:2]([N:19]([CH2:21][CH:22]([OH:29])[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])C)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][N:8]([CH2:10][CH:11]([OH:18])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17])C>>[CH2:2]([NH:19][CH2:21][CH:22]([OH:29])[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][NH:8][CH2:10][CH:11]([OH:18])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17]

Participants

Reactant 2

HCID 260Hydrogen Bromide

HCID 21332414HCID 21332414, compound

Product 1

HCID 21332375HCID 21332375, compound

Procedure

In a manner similar to that of Example 22, methylation of N,N'-(1,6-hexylene)-bis[2-hydroxyoctylamine] (35 g.) and treatment of the resulting product (b.p. 177°-182° C./1 mm.) with hydrogen bromide gave N,N'-(1,6-hexylene)-bis[N-methyl-2- hydroxyoctylamine] (I: R= CH3 (CH2)5, R' = CH3, X= (CH2)6, Z= H) dihydrobromide (19.1 g., m.p. 167.0°-158.8° C.).

Sources & evidence

ORD record: ord-0df200626cad4f3ea7926718e5a9312e
Source dataset: uspto-grants-1977_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04022833

Reaction notes

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