Hydrogen Bromide → N,N'-(1,6-hexylene)-bis[2-hydroxynonylamine]

HRID 2397814Notes

Reaction equation

Br.[CH2:2]([N:20]([CH2:22][CH:23]([OH:31])[CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])C)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][N:8]([CH2:10][CH:11]([OH:19])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])C>>[CH2:2]([NH:20][CH2:22][CH:23]([OH:31])[CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][NH:8][CH2:10][CH:11]([OH:19])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]

Participants

Reactant 2

HCID 260Hydrogen Bromide

HCID 21332463N,N'-(1,6-hexylene)-bis[N-methyl-2-hydroxynonylamine]

Product 1

HCID 21332345N,N'-(1,6-hexylene)-bis[2-hydroxynonylamine]

Procedure

In a manner similar to that of Example 22, methylation of N,N'-(1,6-hexylene)-bis[2-hydroxynonylamine] (36 g.) and treatment of the resulting product (25 g., b.p. 172°-176° C./0.05 mm.) with hydrogen bromide gave N,N'-(1.6-hexylene)-bis[N-methyl-2-hydroxynonylamine] (I: R= CH3 (CH2)6, R' = CH3, X= (CH2)6, Z= H) dihydrobromide (26.3 g., m.p. 176.0° -177.0° C.).

Sources & evidence

ORD record: ord-89ec7abea6054e35aba0f6b3686d977c
Source dataset: uspto-grants-1977_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04022833

Reaction notes

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