1-Nitro-2-nitrosocyclooctane → N-(2-Nitrocyclooctylidene)hydroxylamine

HRID 2398506Notes

Reaction equation

HRID 2398506 reaction equation
[N:1]([CH:3]1[CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH:4]1[N+:11]([O-:13])=[O:12])=[O:2]>O1CCOCC1>[N+:11]([CH:4]1[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][C:3]1=[N:1][OH:2])([O-:13])=[O:12]

Participants

3

Reactant 1

HCID 214356161-Nitro-2-nitrosocyclooctane

Product 1

HCID 71358152N-(2-Nitrocyclooctylidene)hydroxylamine

Reagents, catalysts & solvents 1

HCID 312751,4-DioxaneSolvent

Procedure

1-Nitroso-2-nitrocyclooctane, in a three-fold amount of dioxane, is heated for 2 hours under nitrogen at 100° C, whilst stirring. After removing the solvent on a rotary evaporator, 2-nitro-cyclooctan-1-one-oxime is obtained, in quantitative yield, as a brown oil.

Workup

  1. customAfter removing the solvent
  2. customon a rotary evaporator

Sources & evidence

ORD record
ord-64b4f84d4e2949748987e99f2e383982
Source dataset
uspto-grants-1977_05
Patent number
US04024327

Reaction notes

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