Triphenylphosphine → n-Pentyl-triphenylphosphonium iodide
Reaction equation
[CH2:1]([I:6])[CH2:2][CH2:3][CH2:4][CH3:5].[C:7]1([P:13]([C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1>>[I-:6].[CH2:1]([P+:13]([C:14]1[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1)([C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1)[C:7]1[CH:8]=[CH:9][CH:10]=[CH:11][CH:12]=1)[CH2:2][CH2:3][CH2:4][CH3:5]Participants
3
Procedure
Using the procedure of Step B of Example 1, n-pentyl iodide and triphenylphosphine were reacted to obtain n-pentyl-triphenylphosphonium iodide melting at 174° C.
Workup
- customwere reacted
Sources & evidence
- ORD record
- ord-5f4f50f679eb40ae95d19d47f59f8304
- Source dataset
- uspto-grants-1977_05
- Patent number
- US04027040
Reaction notes
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