1-Bromooctane → HCID 19384567, compound

HRID 2399793Notes

Reaction equation

[C:1]1([CH2:7][O:8][C:9]2[CH:10]=[CH:11][CH2:12][C:13]3[C:17]=2[N:16]=[C:15]2[CH2:18][CH2:19][CH2:20][CH2:21][C:14]=32)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.Br[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30]>>[C:1]1([CH2:7][O:8][C:9]2[CH:10]=[CH:11][CH:12]([CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])[C:13]3[C:17]=2[N:16]=[C:15]2[CH2:18][CH2:19][CH2:20][CH2:21][C:14]=32)[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Participants

Reactant 2

HCID 81401-Bromooctane

HCID 19384476HCID 19384476, compound

Product 1

HCID 19384567HCID 19384567, compoundYield 86.8%

Procedure

Using the procedure of Example 9, 37.4 g of 1,2,3,4-tetrahydro-6-phenylmethoxy-9H-dibenzo[b,d]pyrrole from Example 56 was alkylated with 1-bromooctane (27.9 g; 0.145 mol) giving 45.6 g (86.8%) of 1,2,3,4-tetrahydro-6-phenylmethoxy-9-octyl-9H-dibenzo-[b,d]pyrrole as a yellow oil after chromatographic purification.

Sources & evidence

ORD record: ord-05d5c7fb7b4b487581fcf89d441e561e
Source dataset: uspto-grants-1995_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05451600

Reaction notes

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