1-Bromooctane → HCID 19384551, compound

HRID 2399794Notes

Reaction equation

HRID 2399794 reaction equation
[C:1]1([CH2:7][O:8][C:9]2[CH:10]=[C:11]3[N:15]=[C:14]4[CH2:16][CH2:17][CH2:18][CH2:19][C:13]4=[C:12]3[CH2:20][CH:21]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.Br[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30]>>[C:1]1([CH2:7][O:8][C:9]2[CH:10]=[C:11]3[N:15]=[C:14]4[CH2:16][CH2:17][CH2:18][CH2:19][C:13]4=[C:12]3[CH:20]([CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])[CH:21]=2)[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Participants

3

Reactant 2

HCID 81401-BromooctaneHCID 19384515HCID 19384515, compound

Product 1

HCID 19384551HCID 19384551, compoundYield 92.9%

Procedure

Using the procedure of Example 9, 6.9 g of 1,2,3,4-tetrahydro-7-phenylmethoxy -9H-dibenzo[b,d]pyrrole from Example 57 was alkylated with 1-bromooctane (5.25 g) giving 9.0 g (92.8%) of 1,2,3,4-tetrahydro-7-phenylmethoxy-9-octyl-9H-dibenzo[b,d]pyrrole as a yellow oil after chromatographic purification.

Sources & evidence

ORD record
ord-751e74cfac364ddaaf015b71f8c4c3de
Source dataset
uspto-grants-1995_09
Patent number
US05451600

Reaction notes

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