Ethanol → HCID 86749003, compound

Participants

Reaction Conditions

Reaction Steps

1,30-Triacontadiol (38) (2.5 g, 5.5 mmol) was dissolved in dry, ethanol free chloroform at 60° C. under nitrogen and treated with pyridine (0.49 ml; 6.05 mmol). The resulting solution was treated with a solution of linoleoyl chloride (39) (1.64 g; 5.5 mmol) in chloroform (20 ml) over a twenty minute period and then maintained at 60° C. for a further thirty minutes, then cooled, diluted with chloroform, washed with water three times, dried, filtered and evaporated. The crude product obtained in this manner was purified on silica (30 g). Elution with chloroform gives the title compound (40) as a white solid (1.73 g; 44%).

Provenance & Evidence