HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diazald → HCID 58919487, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diazald | HCID 6628 | — |
| Reactant | tert-Butyl piperazine-1-carboxylate | HCID 143452 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 58919487 | HCID 58919487 | — |
Reaction Steps
To a solution of piperazine-1-carboxylic acid tert-butyl ester (26 mmol) in DCM (130 mL) was added, in one portion, Diazald (4 eq.). After stirring at reflux for 12 h, the solution was cooled, concentrated and the residue was purified by flash chromatography (0-20% EtOAc/Heptane) to afford 4-nitrosopiperazine-1-carboxylic acid tert-butyl ester.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08796256B2 |
| Source dataset | uspto-grants-2014_08 |
| ORD ID | ord-6ca9e92d9a7f4229a696008e2cdee00f |
| Source note | uspto-grants-2014_08 |