HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 18929264, compound → 2-Diisopropylphosphinomethyl-2'-methyl-1,1'-binaphthyl
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 18929264 | HCID 18929264 | — |
| Reactant | Aluminium lithium hydride | HCID 21226445 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | 2-Diisopropylphosphinomethyl-2'-methyl-1,1'-binaphthyl | HCID 19690361 | — |
Reaction Steps
4 g (8.4 mmol) of 4,4-diisopropyl-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]phosphepinium bromide are suspended in 70 ml of absolute toluene under protective gas and reacted with 400 mg (10.5 mmol) of lithium aluminum hydride using a method analogous to Example 5.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05728886 |
| Source dataset | uspto-grants-1998_03 |
| ORD ID | ord-7819582fed694c3f99e1f2746fab150a |
| Source note | uspto-grants-1998_03 |