Lithium hydroxide, monohydrate → HCID 86692778, compound

HRID 2403171Notes

Reaction equation

HRID 2403171 reaction equation
[CH3:1][S:2]([N:5]1[CH2:10][CH2:9][CH:8]([N:11]2[CH2:14][CH2:13][CH:12]2[C:15]([O:17]C)=[O:16])[CH2:7][CH2:6]1)(=[O:4])=[O:3].O.[OH-].[Li+:21]>>[CH3:1][S:2]([N:5]1[CH2:6][CH2:7][CH:8]([N:11]2[CH2:14][CH2:13][CH:12]2[C:15]([O-:17])=[O:16])[CH2:9][CH2:10]1)(=[O:3])=[O:4].[Li+:21]

Participants

3

Reactant 2

HCID 168937Lithium hydroxide, monohydrateHCID 86762594HCID 86762594, compound

Product 1

HCID 86692778HCID 86692778, compound

Procedure

The reaction of methyl 1-(1-(methylsulfonyl)piperidin-4-yl)azetidine-2-carboxylate 19L and lithium hydroxide monohydrate yielded lithium 1-(1-(methylsulfonyl)piperidin-4-yl)azetidine-2-carboxylate as light brown solid (quant.). MS ISP (m/e): 263.1 (100) [(M+H)]+.

Sources & evidence

ORD record
ord-de08c71ea8c3486b9a40b3917f880724
Source dataset
uspto-grants-2014_08
Patent number
US08802665B2

Reaction notes

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