Sodium Azide → HCID 178439046, compound

HRID 2405000Notes

Reaction equation

HRID 2405000 reaction equation
[CH:1]([C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([CH:10]([CH3:12])[CH3:11])[C:5]=1[N:13]=[C:14]([C:16]1[CH:17]=[CH:18][C:19]2[C:20]3[CH:21]=[CH:22][CH:23]=[C:24]4[C:38]=3[C:28]([C:29]3[C:34]=2[C:33]=1[C:32]([C:35]([OH:37])=[O:36])=[CH:31][CH:30]=3)=[CH:27][CH:26]=[C:25]4[C:39]#[C:40][CH2:41][CH2:42][CH2:43][CH2:44]OS(C1C=CC(C)=CC=1)(=O)=O)[OH:15])([CH3:3])[CH3:2].[N-:56]=[N+:57]=[N-:58].[Na+]>CN(C=O)C>[CH:1]([C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([CH:10]([CH3:12])[CH3:11])[C:5]=1[N:13]=[C:14]([C:16]1[CH:17]=[CH:18][C:19]2[C:20]3[CH:21]=[CH:22][CH:23]=[C:24]4[C:38]=3[C:28]([C:29]3[C:34]=2[C:33]=1[C:32]([C:35]([OH:37])=[O:36])=[CH:31][CH:30]=3)=[CH:27][CH:26]=[C:25]4[C:39]#[C:40][CH2:41][CH2:42][CH2:43][CH2:44][N:56]=[N+:57]=[N-:58])[OH:15])([CH3:3])[CH3:2]

Participants

4

Reactant 2

HCID 33557Sodium AzideHCID 178427727HCID 178427727, compound

Product 1

HCID 178439046HCID 178439046, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

A solution of 1.00 g (1.36 mmol) N-(2,6-diisopropylphenyl)-9-(6-tosyloxy-1-hexinyl)-perylene-3,4-dicarboxylic acid imide and 0.60 g (9.1 mmol) sodium azide in 144 ml DMF were stirred for 20 hours at room temperature under nitrogen atmosphere.

Sources & evidence

ORD record
ord-003a7f6b8fe748d5b592976edbadbf39
Source dataset
uspto-grants-2014_08
Patent number
US08802852B2

Reaction notes

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