2,4,6-Trimethoxybenzaldehyde → HCID 68542497, compound

HRID 2405540Notes

Reaction equation

HRID 2405540 reaction equation
[Br:1][C:2]1[CH:7]=[CH:6][C:5]([C:8](=[O:18])[CH2:9][S:10][C:11]2[CH:16]=[CH:15][C:14]([Br:17])=[CH:13][CH:12]=2)=[CH:4][CH:3]=1.[CH3:19][O:20][C:21]1[CH:28]=[C:27]([O:29][CH3:30])[CH:26]=[C:25]([O:31][CH3:32])[C:22]=1[CH:23]=O>>[Br:1][C:2]1[CH:3]=[CH:4][C:5]([C:8](=[O:18])/[C:9](/[S:10][C:11]2[CH:16]=[CH:15][C:14]([Br:17])=[CH:13][CH:12]=2)=[CH:23]\[C:22]2[C:25]([O:31][CH3:32])=[CH:26][C:27]([O:29][CH3:30])=[CH:28][C:21]=2[O:20][CH3:19])=[CH:6][CH:7]=1

Participants

3

Reactant 2

HCID 700192,4,6-TrimethoxybenzaldehydeHCID 43412626HCID 43412626, compound

Product 1

HCID 68542497HCID 68542497, compound

Procedure

The title compound is prepared by the methods described in Synthesis Example 1. A solution of 1-(4-bromophenyl)-2-(4-bromophenylthio)ethanone (10 mmol) and 2,4,6-trimethoxybenzaldehyde (10 mmol) was subjected to the procedure described as Method B in part C of Synthesis Example 1 and the product obtained was purified by column chromatography. m.p 130-132° C.

Workup

  1. customdescribed in Synthesis Example 1
  2. customdescribed as Method B in part C of Synthesis Example 1
  3. customthe product obtained
  4. customwas purified by column chromatography
  5. customm.p 130-132° C.

Sources & evidence

ORD record
ord-912c86346eea4038910917b2ec2c9163
Source dataset
uspto-grants-2014_08
Patent number
US08808702B2

Reaction notes

Loading…