2,3-Dichloroaniline → 2,3-Dichloroaniline

HRID 2413052Notes

Reaction equation

HRID 2413052 reaction equation
[Cl:1][C:2]1[CH:3]=[C:4]([CH:6]=[C:7](Cl)[C:8]=1Cl)[NH2:5].[Cl:11][C:12]1[C:18]([Cl:19])=[CH:17][CH:16]=[CH:15][C:13]=1[NH2:14]>>[Cl:1][C:2]1[CH:3]=[C:4]([CH:6]=[CH:7][CH:8]=1)[NH2:5].[Cl:11][C:12]1[C:18]([Cl:19])=[CH:17][CH:16]=[CH:15][C:13]=1[NH2:14]

Participants

4

Reactant 2

HCID 118442,3-DichloroanilineHCID 124693,4,5-Trichloroaniline

Product 2

HCID 79323-ChloroanilineHCID 118442,3-DichloroanilineYield 100%

Procedure

Example 9 is repeated, the 3,4,5-trichloroaniline being replaced by 2,3-dichloroaniline. After a reaction time of 28 hours under the same conditions, 3-chloroaniline is obtained with a yield of 100% for a degree of conversion of 100% of the 2,3-dichloroaniline. The degree of hydrodechlorination of the solvent is 0.09%.

Sources & evidence

ORD record
ord-4472cd2055bf496b9feff6592b6049ee
Source dataset
uspto-grants-1985_01
Patent number
US04495368

Reaction notes

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