HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethanol → Ethyl bis(pentafluoroethyl)phosphinite
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethanol | HCID 702 | — |
| Reactant | Bis(pentafluoroethyl)phosphinous chloride | HCID 2757428 | — |
| Catalyst | 4-(Dimethylamino)pyridine | HCID 14284 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | Ethyl bis(pentafluoroethyl)phosphinite | HCID 86653812 | — |
Reaction Steps
Bis(pentafluoroethyl)phosphinous acid chloride, (C2F5)2PCl, obtainable in accordance with Example 2, is added to a mixture of ethanol and 4-dimethylaminopyridine in diethyl ether at room temperature. The precipitated product 4-dimethylaminopyridinium chloride is separated off, and the solution comprises ethyl bis(pentafluoroethyl)phosphinite, (C2F5)2POC2H5.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08648202B2 |
| Source dataset | uspto-grants-2014_02 |
| ORD ID | ord-eda27c680cc84ed38fcae7051d4ad4c6 |
| Source note | uspto-grants-2014_02 |