Sodium Hydroxide → HCID 178506339, compound

HRID 241312Notes

Reaction equation

HRID 241312 reaction equation
[F:1][C:2]([P:8](C(F)(F)C(F)(F)F)[C:9]([F:15])([F:14])[C:10]([F:13])([F:12])[F:11])([F:7])[C:3]([F:6])([F:5])[F:4].[OH-:23].[Na+:24]>COCCOC.O>[P:8]([O:23][Na:24])([C:9]([C:10]([F:13])([F:12])[F:11])([F:15])[F:14])[C:2]([C:3]([F:6])([F:5])[F:4])([F:7])[F:1]

Participants

5

Reactant 2

HCID 14798Sodium HydroxideHCID 15809510Tris(pentafluoroethyl)phosphane

Product 1

HCID 178506339HCID 178506339, compound

Reagents, catalysts & solvents 2

HCID 962WaterSolventHCID 80711,2-DimethoxyethaneSolvent

Procedure

A solution of 1.16 g (3.0 mmol) of tris(pentafluoroethyl)phosphine, (C2F5)3PH, in 1,2-dimethoxyethane is treated with an excess (6 mmol) of a 1.5 M solution of NaOH in water. The mixture is stirred at room temperature for 30 min, and the solvent is subsequently removed in vacuo, giving a colourless residue, sodium bis(pentafluoroethyl)phosphinite, (C2F5)2PONa.

Workup

  1. customthe solvent is subsequently removed in vacuo

Sources & evidence

ORD record
ord-58f4381b1b6e4696a438de74806e17dd
Source dataset
uspto-grants-2014_02
Patent number
US08648202B2

Reaction notes

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