HCID 21276215, compound → (10-Bromo-1-anthracenyl)methanol

HRID 2413614Notes

Reaction equation

HRID 2413614 reaction equation
[Br:1][C:2]1[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[CH:9]=[C:8]2[C:3]=1[CH:4]=[CH:5][CH:6]=[C:7]2[C:16](O)=[O:17]>C1COCC1>[Br:1][C:2]1[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[CH:9]=[C:8]2[C:3]=1[CH:4]=[CH:5][CH:6]=[C:7]2[CH2:16][OH:17]

Participants

3

Reactant 1

HCID 21276215HCID 21276215, compound

Product 1

HCID 13375398(10-Bromo-1-anthracenyl)methanol

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

10-Bromo-1-anthracenecarboxylic acid made from example 2B by the procedure of E. Barnett, J. W. Cook, and H. H. Grainger, Ber. 57 B, 1775 (1924), was reduced with BH3 in THF by the procedure outlined in 2C to give (10-bromo-1-anthryl)methanol mp 125°-127°, (EtOAc/hexane), (C,H,Br).

Sources & evidence

ORD record
ord-862fc819030042d3a249162fcf342e6d
Source dataset
uspto-grants-1988_01
Patent number
US04719047

Reaction notes

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