1-Chloroanthraquinone → HCID 13375396, compound
Reaction equation
[Cl:1][C:2]1[C:15]2[C:6](=[CH:7][C:8]3[C:13]([CH:14]=2)=[CH:12][CH:11]=[CH:10][CH:9]=3)[CH:5]=[CH:4][CH:3]=1.ClC1C2[C:29](=[O:31])C3C(=CC=CC=3)C(=O)C=2C=CC=1>>[Cl:1][C:2]1[C:15]2[C:6](=[C:7]([CH:29]=[O:31])[C:8]3[C:13]([CH:14]=2)=[CH:12][CH:11]=[CH:10][CH:9]=3)[CH:5]=[CH:4][CH:3]=1Participants
3
Procedure
1-Chloroanthracene prepared from 1-chloroanthraquinone (Aldrich) by the method of H. O. House et. al. (J. Org. Chem. 38 1167 (1973)) was formylated by the procedure outlined in 14A to give 4-chloro-9-anthracenecarbaldehyde mp 129°-131°, (PhCH3 /CH3OH), (C,H,Cl).
Sources & evidence
- ORD record
- ord-57c894925f03448eba0cc85769d307f9
- Source dataset
- uspto-grants-1988_01
- Patent number
- US04719047
Reaction notes
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