Ethanol → 10-Ethoxy-9-anthracenecarbaldehyde

HRID 2413623Notes

Reaction equation

HRID 2413623 reaction equation
[CH3:1][CH2:2][O-:3].[Na+].CCO.Cl[C:9]1[C:22]2[C:17](=[CH:18][CH:19]=[CH:20][CH:21]=2)[C:16]([CH:23]=[O:24])=[C:15]2[C:10]=1[CH:11]=[CH:12][CH:13]=[CH:14]2>C(Cl)Cl.CCCCCC>[CH2:2]([O:3][C:9]1[C:22]2[C:17](=[CH:18][CH:19]=[CH:20][CH:21]=2)[C:16]([CH:23]=[O:24])=[C:15]2[C:10]=1[CH:11]=[CH:12][CH:13]=[CH:14]2)[CH3:1]

Participants

5

Reactant 3

HCID 702EthanolHCID 8270310-Chloro-9-anthraldehydeHCID 2723922Sodium ethoxide

Product 1

HCID 1337540410-Ethoxy-9-anthracenecarbaldehyde

Reagents, catalysts & solvents 1

HCID 21226440Methylenechloride HexaneSolvent

Procedure

Using the procedure outlined in 11A, except that NaOEt (Aldrich)/EtOH was used instead of NaOCH3 /CH3OH, 10-chloro-9-anthraldehyde (Aldrich) gave 10-ethoxy-9-anthracenecarbaldehyde mp 88°-90°, (CH2Cl2 /hexane) (C,H).

Sources & evidence

ORD record
ord-48cfe5fe2f0c4ea483d9a6407c7023ca
Source dataset
uspto-grants-1988_01
Patent number
US04719047

Reaction notes

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