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HRID2416411

反应详情

EQUATION

反应方程式

HRID 2416411 的结构方程式

REACTANTS

反应物

3
结构：OC1C(O)C(O)C(O)C(O)C1O
HCID892

Inositol

C6H12O6

2 次

结构：OC[C@H]1O[C@H](OC2[C@@H](O)[C@@H](O)C(O)[C@H](O)[C@H]2O)[C@H](O)[C@@H](O)[C@H]1O
HCID9840967

未命名化合物

结构：OC[C@H]1O[C@H](OC2[C@@H](O)[C@H](O)C(O)[C@@H](O)[C@@H]2O)[C@H](O)[C@@H](O)[C@H]1O
HCID9906026

未命名化合物

PRODUCTS

生成物

3
结构：OC1C(O)C(O)C(O)C(O)C1O
HCID892

Inositol

C6H12O6

结构：O=C[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)CO
HCID3037556

(2R,3S,4S,5R)-2,3,4,5,6-pentahydroxyhexanal

C6H12O6

结构：OC[C@H]1O[C@H](OC2[C@@H](O)[C@@H](O)C(O)[C@H](O)[C@H]2O)[C@H](O)[C@@H](O)[C@H]1O
HCID9840967

未命名化合物

PROCEDURE

实验过程

Results. Buckwheat bran was extracted with 50% EtOH, and the resulting extract chromatographed on carbon-Celite, 1:1 (w/w), to purify Fagopyritol A1. Fagopyritol B1 was also purified from the same sample for comparison. Per(pentafluoropropionates) of chiro-inositol from acid hydrolysis of Fagopyritol A1 and Fagopyritol B1 co-chromatographed on a chiral column with authentic D-chiro-inositol, but not with authentic L-chiro-inositol. Hydrolysis of Fagopyritol A1 and Fagopyritol B1 produced D-galactose and D-chiro-inositol in mole ratios of 1.01:1.00 for Fagopyritol A1 and 1.03:1.00 for Fagopyritol B11. Free D-chiro-inositol was obtained by acid hydrolysis of a mixture of Fagopyritol A1 and Fagopyritol B1 followed by purification on a carbon-Celite column. Fagopyritol A1 and Fagopyritol B1 were hydrolyzed by β-D-galactosidase, but not by β-D-galactosidase, demonstrating an α-D-galactopyranosyl linkage.

WORKUP

后处理

  1. customResults
  2. extractionBuckwheat bran was extracted with 50% EtOH
  3. extractionthe resulting extract
  4. customchromatographed on carbon-Celite, 1:1 (w/w)
  5. customto purify Fagopyritol A1
  6. customFagopyritol B1 was also purified from the same sample for comparison
  7. customPer(pentafluoropropionates) of chiro-inositol from acid hydrolysis of Fagopyritol A1 and Fagopyritol B1