1,2-Dihydronaphthalene → HCID 22633317, compound

HRID 2417392Notes

Reaction equation

HRID 2417392 reaction equation
[C:1]([C:3]1[CH:8]=[CH:7][C:6]([NH2:9])=[CH:5][CH:4]=1)#[N:2].[CH2:10]1[C:19]2[C:14](=[CH:15][CH:16]=[CH:17][CH:18]=2)[CH:13]=[CH:12][CH2:11]1.C([O:23][C:24]1[CH:31]=[CH:30][C:27]([CH:28]=O)=[CH:26][C:25]=1[O:32][CH3:33])(=O)C>>[OH:23][C:24]1[CH:31]=[CH:30][C:27]([CH:28]2[CH:16]3[CH:15]([C:14]4[CH:13]=[CH:12][CH:11]=[CH:10][C:19]=4[CH2:18][CH2:17]3)[C:5]3[CH:4]=[C:3]([C:1]#[N:2])[CH:8]=[CH:7][C:6]=3[NH:9]2)=[CH:26][C:25]=1[O:32][CH3:33]

Participants

4

Reactant 3

HCID 99381,2-DihydronaphthaleneHCID 133964-AminobenzonitrileHCID 61229Vanillin acetate

Product 1

HCID 22633317HCID 22633317, compound

Procedure

6-(4-Hydroxy-3-methoxy-phenyl)-5,6,6a,7,8,12b-hexahydro-benzo[k]phenanthridine-2-carbonitrile was prepared according to the protocol described in Example 2 using 4-cyanophenyl amine instead of 4-amino-benzamidine mono HCl salt, 1,2-dihydronapthalene and 4-acetoxy-3-methoxybenzaldehyde. Mass spectrum 400 (M+1).

Sources & evidence

ORD record
ord-bf3816ac1747401e8b05dee9a1909672
Source dataset
uspto-grants-2004_11
Patent number
US06825208B2

Reaction notes

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