HuagongsheHuagongshe Chemistry Print Report · For research reference only
Lithium → HCID 53825399, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Lithium | HCID 3028194 | — |
| Reactant | 2-[4-(4-Trifluoromethylphenoxy)phenoxy]propanal | HCID 12856781 | — |
| Reactant | 2-butanone N,N-dimethylhydrazone | HCID 54429110 | — |
| Product | HCID 53825399 | HCID 53825399 | — |
Reaction Steps
Following the procedure of Example 1, 2-[4-(4-trifluoromethylphenoxy)phenoxy]propanal is reacted with the lithium salt of 2-butanone N,N-dimethylhydrazone to give 5-hydroxy-6-[4-(4-trifluoromethylphenoxy)phenoxy]-3-heptanone N,N-dimethylhydrazone (cpd. 9, Table A). This hydrazone is then hydrolyzed to 5-hydroxy-6-[4-(4-trifluoromethylphenoxy)phenoxy]-3-heptanone (cpd. 9, Table B).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04469872 |
| Source dataset | uspto-grants-1984_09 |
| ORD ID | ord-47d848c234ab4dfb8188f81b9e3d6f12 |
| Source note | uspto-grants-1984_09 |