m-Chloroperbenzoic acid → HCID 178493208, compound

HRID 2418244Notes

Reaction equation

HRID 2418244 reaction equation
[F:1][C:2]([F:23])([F:22])[C:3]1[CH:21]=[CH:20][C:6]2[NH:7][C:8]([S:10][CH2:11][C:12]3[CH:17]=[C:16]([O:18][CH3:19])[CH:15]=[CH:14][N:13]=3)=[N:9][C:5]=2[CH:4]=1.ClC1C=C(C=CC=1)C(OO)=[O:29]>>[F:23][C:2]([F:1])([F:22])[C:3]1[CH:21]=[CH:20][C:6]2[NH:7][C:8]([S:10]([CH2:11][C:12]3[CH:17]=[C:16]([O:18][CH3:19])[CH:15]=[CH:14][N:13]=3)=[O:29])=[N:9][C:5]=2[CH:4]=1

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 178493199HCID 178493199, compound

Product 1

HCID 178493208HCID 178493208, compound

Procedure

0.1 g of the title compound of m.p. 166° C. (with decomposition, recrystallized twice from isopropanol) is obtained, by a method analogous to that in Example 1, starting from 0.3 g (0.92 mole) of 5-trifluoromethyl-2-[(4-methoxy-2-pyridylmethyl)thio]-(1H)-benzimidazole and 0.3 g of 85% strength m-chloroperoxybenzoic acid.

Workup

  1. custom0.1 g of the title compound of m.p. 166° C. (with decomposition, recrystallized twice from isopropanol)
  2. customis obtained, by a method analogous to that in Example 1

Sources & evidence

ORD record
ord-fd3f8fe68b4c4f2eae906209c82a83a0
Source dataset
uspto-grants-1984_09
Patent number
US04472409

Reaction notes

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