Thionyl Chloride → HCID 13189989, compound

HRID 2418279Notes

Reaction equation

HRID 2418279 reaction equation
[CH2:1]([CH:5]([CH2:8][C:9]1[CH:14]=[CH:13][C:12]([Cl:15])=[C:11]([Cl:16])[C:10]=1[Cl:17])[CH2:6]O)[CH2:2][CH2:3][CH3:4].S(Cl)([Cl:20])=O>>[CH2:1]([CH:5]([CH2:8][C:9]1[CH:14]=[CH:13][C:12]([Cl:15])=[C:11]([Cl:16])[C:10]=1[Cl:17])[CH2:6][Cl:20])[CH2:2][CH2:3][CH3:4]

Participants

3

Reactant 2

HCID 24386Thionyl ChlorideHCID 13189988HCID 13189988, compound

Product 1

HCID 13189989HCID 13189989, compoundYield 78.8%

Conditions

Temperature
140 °C

Procedure

332 g of (XX) were added dropwise to 148 g of thionyl chloride, and the mixture was stirred for 14 hours at room temperature and for 2 hours at 140° C. Distillation gave 278 g of (XXI) of boiling point 142°-145° C./0.1 mbar.

Workup

  1. distillationDistillation

Sources & evidence

ORD record
ord-b5423466a6314bcca98fe7e4f4bc96ca
Source dataset
uspto-grants-1984_09
Patent number
US04472412

Reaction notes

Loading…