Potassium Carbonate → Ethyl 2-[2-nitro-3-(3,5-dichlorophenoxy)phenyl]acetate

HRID 2418327Notes

Reaction equation

HRID 2418327 reaction equation
[N+:1]([C:4]1[C:9](Cl)=[CH:8][CH:7]=[CH:6][C:5]=1[CH2:11][C:12]([O:14][CH2:15][CH3:16])=[O:13])([O-:3])=[O:2].[Cl:17][C:18]1[CH:19]=[C:20]([OH:25])[CH:21]=[C:22]([Cl:24])[CH:23]=1.C(=O)([O-])[O-].[K+].[K+]>>[N+:1]([C:4]1[C:9]([O:25][C:20]2[CH:19]=[C:18]([Cl:17])[CH:23]=[C:22]([Cl:24])[CH:21]=2)=[CH:8][CH:7]=[CH:6][C:5]=1[CH2:11][C:12]([O:14][CH2:15][CH3:16])=[O:13])([O-:3])=[O:2]

Participants

4

Reactant 3

HCID 11430Potassium CarbonateHCID 115713,5-DichlorophenolHCID 20446267Ethyl 2-(3-chloro-2-nitrophenyl)acetate

Product 1

HCID 20446287Ethyl 2-[2-nitro-3-(3,5-dichlorophenoxy)phenyl]acetate

Procedure

A mixture of ethyl 2-(2-nitro-3-chlorophenyl)acetate (10 g.), 3,5-dichlorophenol (7.4 g.), anhydrous potassium carbonate (8.5 g.) and cupric oxide (1 g.) was treated in a similar manner to the above to give oil of the captioned compound (7.6 g.).

Workup

  1. additionwas treated in a similar manner to the above
  2. customto give oil of the captioned compound (7.6 g.)

Sources & evidence

ORD record
ord-e5b4631744b448118ac3b8faef146692
Source dataset
uspto-grants-1984_09
Patent number
US04472433

Reaction notes

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