Sodium benzenethiolate → HCID 20446162, compound

HRID 2418332Notes

Reaction equation

HRID 2418332 reaction equation
[N+:1]([C:4]1[C:9](Cl)=[CH:8][CH:7]=[CH:6][C:5]=1[CH2:11][C:12]([O:14][CH2:15][CH3:16])=[O:13])([O-:3])=[O:2].[C:17]1([S-:23])[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1.[Na+]>CN(C)C=O>[N+:1]([C:4]1[C:9]([S:23][C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=2)=[CH:8][CH:7]=[CH:6][C:5]=1[CH2:11][C:12]([O:14][CH2:15][CH3:16])=[O:13])([O-:3])=[O:2]

Participants

4

Reactant 2

HCID 4110039Sodium benzenethiolateHCID 20446267Ethyl 2-(3-chloro-2-nitrophenyl)acetate

Product 1

HCID 20446162HCID 20446162, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

A mixture of ethyl 2-(2-nitro-3-chlorophenyl)acetate (8.4 g.), sodium benzenethiolate (4.6 g.), and dimethylformamide (50 ml.) was treated in a similar manner to the above to give yellow needles of the captioned compound (7.25 g.). mp 65° to 67° C.

Workup

  1. additionwas treated in a similar manner to the above
  2. customto give yellow needles of the captioned compound (7.25 g.)

Sources & evidence

ORD record
ord-87b29d0fcec64a9398593533a90d5159
Source dataset
uspto-grants-1984_09
Patent number
US04472433

Reaction notes

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