m-Chloroperbenzoic acid → HCID 20446146, compound

HRID 2418339Notes

Reaction equation

HRID 2418339 reaction equation
[O:1]=[C:2]1[CH2:10][C:9]2[C:4](=[C:5]([S:11][C:12]3[CH:17]=[CH:16][CH:15]=[CH:14][C:13]=3[Cl:18])[CH:6]=[CH:7][CH:8]=2)[NH:3]1.ClC1C=CC=C(C(OO)=[O:27])C=1>C(Cl)(Cl)Cl>[O:1]=[C:2]1[CH2:10][C:9]2[C:4](=[C:5]([S:11]([C:12]3[CH:17]=[CH:16][CH:15]=[CH:14][C:13]=3[Cl:18])=[O:27])[CH:6]=[CH:7][CH:8]=2)[NH:3]1

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 20446145HCID 20446145, compound

Product 1

HCID 20446146HCID 20446146, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

A solution of 2-oxo-7-(2-chlorophenylthio)indoline (1.0 g.) in chloroform (20 ml.) and m-chloroperbenzoic acid (purity: 85%, 0.73 g.) was treated in a similar manner to that of the Preparation 28-(2) to give crystals of the captioned compound (0.7 g.). mp 243° to 245° C.

Workup

  1. customof the Preparation 28-(2)
  2. customto give crystals of the captioned compound (0.7 g.)

Sources & evidence

ORD record
ord-4e18d93095bd4980a21d4eed908160ce
Source dataset
uspto-grants-1984_09
Patent number
US04472433

Reaction notes

Loading…