Ammonium Chloride → HCID 20446151, compound

HRID 2418345Notes

Reaction equation

HRID 2418345 reaction equation
[Cl-].[NH4+].[N+:3]([C:6]1[C:11]([O:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][C:14]=2[Cl:19])=[CH:10][CH:9]=[CH:8][C:7]=1[CH2:20][C:21]([O:23][CH2:24][CH3:25])=[O:22])([O-])=O>[Fe].O>[NH2:3][C:6]1[C:11]([O:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][C:14]=2[Cl:19])=[CH:10][CH:9]=[CH:8][C:7]=1[CH2:20][C:21]([O:23][CH2:24][CH3:25])=[O:22]

Participants

5

Reactant 2

HCID 25517Ammonium ChlorideHCID 20446173HCID 20446173, compound

Product 1

HCID 20446151HCID 20446151, compound

Reagents, catalysts & solvents 2

HCID 23925IronCatalystHCID 962WaterSolvent

Procedure

A mixture of iron powder (4.2 g.), ammonium chloride (0.42 g.), ethaol (60 ml.) and water (30 ml.) and ethyl 2-[2-nitro-3-(2-chlorophenoxy)phenyl]acetate (5 g.) were treated in a similar manner to that of Example 1-(1) to give oily captioned compound (4.3 g.).

Workup

  1. additionwere treated in a similar manner to that of Example 1-(1)
  2. customto give oily captioned compound (4.3 g.)

Sources & evidence

ORD record
ord-4a603d93d4324c66a4802c455baa165e
Source dataset
uspto-grants-1984_09
Patent number
US04472433

Reaction notes

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