m-Chloroperbenzoic acid → HCID 20446255, compound

HRID 2418387Notes

Reaction equation

HRID 2418387 reaction equation
[O:1]=[C:2]1[CH2:10][C:9]2[C:4](=[C:5]([S:11][C:12]3[CH:17]=[CH:16][C:15]([Cl:18])=[CH:14][CH:13]=3)[CH:6]=[CH:7][CH:8]=2)[NH:3]1.ClC1C=CC=C(C(OO)=[O:27])C=1>C(Cl)(Cl)Cl>[O:1]=[C:2]1[CH2:10][C:9]2[C:4](=[C:5]([S:11]([C:12]3[CH:17]=[CH:16][C:15]([Cl:18])=[CH:14][CH:13]=3)=[O:27])[CH:6]=[CH:7][CH:8]=2)[NH:3]1

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 20446246HCID 20446246, compound

Product 1

HCID 20446255HCID 20446255, compoundYield 52%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

A solution of 2-oxo-7-(4-chlorophenylthio)indoline (7.0 g) in chloroform (400 ml) and m-chloroperbenzoic acid (5.15 g) were treated in a similar manner to that of Preparation 28-(2) to give 2-oxo-7-(4-chlorophenylsulfinyl)indoline (3.85 g). mp 191°-194° C.

Workup

  1. customof Preparation 28-(2)

Sources & evidence

ORD record
ord-fe9aa68f47e64ea0ad46944aca68ef48
Source dataset
uspto-grants-1984_09
Patent number
US04472433

Reaction notes

Loading…