HCID 20446253, compound → HCID 23706954, compound

HRID 2418394Notes

Reaction equation

HRID 2418394 reaction equation
[N+:1]([C:4]1[C:9]([O:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][C:12]=2[Cl:17])=[CH:8][CH:7]=[CH:6][C:5]=1[CH2:18][C:19]([O-:21])=[O:20])([O-])=O.[Na+:22]>[Ni]>[NH2:1][C:4]1[C:9]([O:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][C:12]=2[Cl:17])=[CH:8][CH:7]=[CH:6][C:5]=1[CH2:18][C:19]([O-:21])=[O:20].[Na+:22]

Participants

3

Reactant 1

HCID 20446253HCID 20446253, compound

Product 1

HCID 23706954HCID 23706954, compound

Reagents, catalysts & solvents 1

HCID 935NickelCatalyst

Procedure

Thus obtained sodium 2-[2-nitro-3-(2-chlorophenoxy)phenyl]acetate was subjected successively to catalytic reduction using Raney nickel to give sodium 2-[2-amino-3-(2-chlorophenoxy)phenyl]acetate. This product was identified with crop obtained in Example 5-(2) by I.R. and N.M.R. spectra.

Sources & evidence

ORD record
ord-902959e65aa544acba717998b4250c7c
Source dataset
uspto-grants-1984_09
Patent number
US04472433

Reaction notes

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