Ethanol → HCID 13339995, compound

HRID 2418690Notes

Reaction equation

HRID 2418690 reaction equation
[CH3:1][C:2]1[CH:17]=[C:16]([CH3:18])[CH:15]=[CH:14][C:3]=1[CH:4]=[N:5][C:6]1[CH:11]=[CH:10][C:9]([Cl:12])=[CH:8][C:7]=1[Cl:13].[BH4-].[Na+].C(O)C>O>[CH3:1][C:2]1[CH:17]=[C:16]([CH3:18])[CH:15]=[CH:14][C:3]=1[CH2:4][NH:5][C:6]1[CH:11]=[CH:10][C:9]([Cl:12])=[CH:8][C:7]=1[Cl:13]

Participants

5

Reactant 3

HCID 702EthanolHCID 4311764Sodium borohydrideHCID 1333998888450-60-6

Product 1

HCID 13339995HCID 13339995, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A mixture of 13.9 g. of N-(2,4-dimethylbenzylidene)-2,4-dichloroaniline, 1.89 g. of sodium borohydride and 150 ml of ethanol is stirred under reflux for one hour, allowed to cool and poured into water. Recrystallization from ethanol yields N-(2,4-dimethylbenzyl)-2,4-dichloroaniline, m.p. 88°-90°.

Workup

  1. additionA mixture of 13.9 g
  2. temperatureunder reflux for one hour
  3. temperatureto cool
  4. customRecrystallization from ethanol

Sources & evidence

ORD record
ord-de7cd5887c054836bf4d3a27bf8b0c5c
Source dataset
uspto-grants-1984_09
Patent number
US04473579

Reaction notes

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