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HRID2418950

反应详情

EQUATION

反应方程式

HRID 2418950 的结构方程式

REACTANTS

反应物

3
结构：CC(C)=O
HCID180

Acetone

C3H6O

结构：O=C(CO)[C@@H](O)[C@H](O)[C@H](O)CO
HCID5984

未命名化合物

结构：CCCCC
HCID8003

Pentane

C5H12

PRODUCTS

生成物

1
结构：CC1(C)O[C@@H]2[C@@H](CO[C@@]3(CO)OC(C)(C)O[C@@H]23)O1
HCID10244345

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：O
溶剂HCID962

Water

H2O

CONDITIONS

反应条件

温度
0 °C

PROCEDURE

实验过程

A mixture of 200 grams of D-fructose, 2 liters of acetone, 2 liters of pentane and 8 grams of ferric chloride is stirred and heated to reflux temperature. The reaction water is condensed and removed using a Dean-Stark type water separator. After the theoretical amount of water is removed, the mixture is cooled to 0° C., neutralized with 7 grams of sodium hydroxide in 10 milliliters of water and filtered. The filtrate is treated with 10 grams Norite SG, refiltered, and then concentrated to a syrup which is crystallized from ether-pentane to give 164.4 grams of product, m.p. 94°-95° C.

WORKUP

后处理

  1. temperatureheated
  2. temperatureto reflux temperature
  3. customcondensed
  4. customremoved
  5. customAfter the theoretical amount of water is removed
  6. filtrationfiltered
  7. additionThe filtrate is treated with 10 grams Norite SG
  8. concentrationconcentrated to a syrup which
  9. customis crystallized from ether-pentane