HRID2418962

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID996

Phenol

C6H6O

HCID7597

Diphenylcarbonate

C13H10O3

HCID11430

Potassium Carbonate

CK2O3

结构：Cc1cc(O)c(C(C)(C)C)cc1C(C)CC(c1cc(C(C)(C)C)c(O)cc1C)c1cc(C(C)(C)C)c(O)cc1C

HCID92905

Phenol, 4,4',4''-(1-methyl-1-propanyl-3-ylidene)tris 2-(1,1-dimethylethyl)-5-methyl-

C37H52O3

PRODUCTS

生成物

结构：Cc1cc(O)c(C(C)(C)C)cc1C(C)CC(c1cc(C(C)(C)C)c(O)cc1C)c1cc(C(C)(C)C)c(O)cc1C.O=C(O)O

HCID86735873

未命名化合物

PROCEDURE

实验过程

27.2g (0.05 mole) of 1,1,3-tris(2'-methyl-4'-hydroxy -5'-t-butylphenyl) butane, 8.6g (0.04 mole) of diphenylcarbonate and 0.05g of potassium carbonate were reacted under N2 atmosphere at 150° C for 3 hours, and then phenol was distilled off under reduced pressure (max. 160° C/3 mm Hg) to obtain a glassy solid. Distilled phenol residue after cooling was 100% of the calculated quantity and the molecular weight of the product was 2740 (calculated value: 2824).

WORKUP

后处理

distillationphenol was distilled off under reduced pressure (max. 160° C/3 mm Hg)
customto obtain a glassy solid

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-1a07bf55356a4494bbdcde35bb1ffa43
来源数据集: uspto-grants-1978_08
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04104217
来源说明: uspto-grants-1978_08

反应 SMILES

[CH3:1][C:2]1[CH:7]=[C:6]([OH:8])[C:5]([C:9]([CH3:12])([CH3:11])[CH3:10])=[CH:4][C:3]=1[CH:13]([C:29]1[CH:34]=[C:33]([C:35]([CH3:38])([CH3:37])[CH3:36])[C:32]([OH:39])=[CH:31][C:30]=1[CH3:40])[CH2:14][CH:15]([C:17]1[CH:22]=[C:21]([C:23]([CH3:26])([CH3:25])[CH3:24])[C:20]([OH:27])=[CH:19][C:18]=1[CH3:28])[CH3:16].C1([O:47][C:48](=[O:56])[O:49]C2C=CC=CC=2)C=CC=CC=1.C(=O)([O-])[O-].[K+].[K+].C1(O)C=CC=CC=1>>[C:48](=[O:47])([OH:56])[OH:49].[CH3:40][C:30]1[CH:31]=[C:32]([OH:39])[C:33]([C:35]([CH3:36])([CH3:37])[CH3:38])=[CH:34][C:29]=1[CH:13]([C:3]1[CH:4]=[C:5]([C:9]([CH3:12])([CH3:11])[CH3:10])[C:6]([OH:8])=[CH:7][C:2]=1[CH3:1])[CH2:14][CH:15]([C:17]1[CH:22]=[C:21]([C:23]([CH3:24])([CH3:26])[CH3:25])[C:20]([OH:27])=[CH:19][C:18]=1[CH3:28])[CH3:16]