Potassium Hydroxide → HCID 23670399, compound

HRID 2418983Notes

Reaction equation

HRID 2418983 reaction equation
[CH:1]1[C:11]2[CH2:10][CH2:9][C:8]3[CH:12]=[CH:13][CH:14]=[CH:15][C:7]=3[S:6][C:5]=2[CH:4]=[CH:3][C:2]=1[CH2:16][C:17]([OH:19])=[O:18].[OH-].[K+:21]>CO>[CH:1]1[C:11]2[CH2:10][CH2:9][C:8]3[CH:12]=[CH:13][CH:14]=[CH:15][C:7]=3[S:6][C:5]=2[CH:4]=[CH:3][C:2]=1[CH2:16][C:17]([O-:19])=[O:18].[K+:21]

Participants

4

Reactant 2

HCID 14797Potassium HydroxideHCID 12443712HCID 12443712, compound

Product 1

HCID 23670399HCID 23670399, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

A solution of 350 mg. of 10,11-dihydrodibenzo[b.f]-thiepin-2-acetic acid in five ml. of methanol is treated with 1.1 molar equivalents of 1N methanolic potassium hydroxide. The solvent is evaporated under reduced pressure and the residue taken up in 2 ml. of methanol, followed by precipitation with ether, to yield potassium 10,11-dihydrodibenzo[b.f]thiepin-2-acetate.

Workup

  1. customThe solvent is evaporated under reduced pressure
  2. customof methanol, followed by precipitation with ether

Sources & evidence

ORD record
ord-12047bbc02764a0a9ae7d50c0e4210cc
Source dataset
uspto-grants-1978_08
Patent number
US04104280

Reaction notes

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