Calcium Carbonate → HCID 20316457, compound

HRID 2418984Notes

Reaction equation

HRID 2418984 reaction equation
[CH:1]1[C:11]2[CH2:10][CH2:9][C:8]3[CH:12]=[CH:13][CH:14]=[CH:15][C:7]=3[S:6][C:5]=2[CH:4]=[CH:3][C:2]=1[CH2:16][C:17]([OH:19])=[O:18].[OH-].[Na+].[Cl-].[NH4+].C(=O)([O-])[O-].[Ca+2:28]>Cl>[CH:1]1[C:11]2[CH2:10][CH2:9][C:8]3[CH:12]=[CH:13][CH:14]=[CH:15][C:7]=3[S:6][C:5]=2[CH:4]=[CH:3][C:2]=1[CH2:16][C:17]([O-:19])=[O:18].[Ca+2:28].[CH:1]1[C:11]2[CH2:10][CH2:9][C:8]3[CH:12]=[CH:13][CH:14]=[CH:15][C:7]=3[S:6][C:5]=2[CH:4]=[CH:3][C:2]=1[CH2:16][C:17]([O-:19])=[O:18]

Participants

6

Reactant 4

HCID 10112Calcium CarbonateHCID 14798Sodium HydroxideHCID 25517Ammonium ChlorideHCID 12443712HCID 12443712, compound

Product 1

HCID 20316457HCID 20316457, compound

Reagents, catalysts & solvents 1

HCID 313Hydrochloric AcidSolvent

Procedure

Three hundred milligrams of 10,11-dihydrodibenzo[b.f]thiepin-2-acetic acid are dissolved in an excess of 1N aqueous sodium hydroxide and the resultant solution is buffered with 0.3 g. of ammonium chloride. The buffered solution is added to a solution of 200mg. of calcium carbonate in 1N aqueous hydrochloric acid. The formed precipitate is collected by filtration, washed consecutively with water, dimethoxyethane and ether, to yield calcium 10,11-dihydrodibenzo[b.f]thiepin-2-acetate.

Workup

  1. additionThe buffered solution is added to a solution of 200mg
  2. filtrationThe formed precipitate is collected by filtration
  3. washwashed consecutively with water, dimethoxyethane and ether

Sources & evidence

ORD record
ord-29d215c6fab447268869ec81018d885d
Source dataset
uspto-grants-1978_08
Patent number
US04104280

Reaction notes

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