Methyl iodide → HCID 20313856, compound

HRID 2419125Notes

Reaction equation

HRID 2419125 reaction equation
[CH3:1][O:2][C:3]1[CH:18]=[CH:17][C:6]2[S:7][C:8](=[N:10][C:11]3[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=3)[S:9][C:5]=2[CH:4]=1.[CH3:19][I:20]>>[I-:20].[CH3:1][O:2][C:3]1[CH:18]=[CH:17][C:6]2[S:7][C:8](=[N+:10]([CH3:19])[C:11]3[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=3)[S:9][C:5]=2[CH:4]=1

Participants

3

Reactant 2

HCID 6328Methyl iodideHCID 20313842HCID 20313842, compound

Product 1

HCID 20313856HCID 20313856, compound

Procedure

A solution of N-(5-methoxy-1,3-benzodithiol-2-ylidene)benzenamine (4.5 g) in 100 ml of methyl iodide is heated at reflux for three days. The resultant precipitate is collected by filtration and recrystallized from acetonitrile/benzene to yield 6 g of the title compound, melting point 199° C.

Workup

  1. temperatureat reflux for three days
  2. filtrationThe resultant precipitate is collected by filtration
  3. customrecrystallized from acetonitrile/benzene

Sources & evidence

ORD record
ord-b2830ff89052490aa29572b6cc920d80
Source dataset
uspto-grants-1978_08
Patent number
US04104467

Reaction notes

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